Internal energy and heat transfer
- Internal energy is the total kinetic and potential energy of all the particles in a system.
- Heating increases the internal energy: it either raises the temperature (the particles move faster) or changes the state (the forces between the particles are overcome).
- Conduction: particles vibrate and pass energy to their neighbours. It is fastest in solids, especially metals.
- Convection: in liquids and gases, the warmer part expands, becomes less dense and rises, and cooler fluid sinks, making a convection current.
- Radiation: infrared waves transfer energy without particles, even through a vacuum. Dark, matt surfaces are the best emitters and absorbers; shiny, light surfaces are the worst, and reflect infrared.
Reducing heat loss
- Homes lose less energy with loft insulation, cavity wall insulation, double glazing and draught excluders. Insulating materials trap air, which reduces conduction and convection.
- A vacuum flask keeps drinks hot because the vacuum stops conduction and convection, and the shiny walls reduce radiation.
Specific heat capacity
- Specific heat capacity is the energy needed to raise the temperature of 1 kg of a substance by 1 °C.
- Energy = mass × specific heat capacity × temperature change (E = m × c × Δθ).
- Water has a high specific heat capacity (4200 J/kg°C), so it takes a lot of energy to heat up. Heating 2 kg of water by 10 °C needs 2 × 4200 × 10 = 84 000 J.
- To measure it, heat a metal block of known mass with an electric heater, measure the energy supplied and the temperature rise, then calculate c = E ÷ (m × Δθ). Insulate the block to reduce energy losses.
Specific latent heat
- Specific latent heat is the energy needed to change the state of 1 kg of a substance without changing its temperature: energy = mass × specific latent heat (E = m × L).
- Latent heat of fusion is for melting; latent heat of vaporisation is for boiling.
- While a substance changes state, its temperature stays the same, which shows as a flat section on a heating curve.
Key terms
- Internal energy
- The total kinetic and potential energy of the particles in a system.
- Conduction
- Energy transfer through a material by particles passing on vibrations.
- Convection
- Energy transfer by the movement of a warm liquid or gas.
- Radiation
- Energy transfer by infrared waves, which can cross a vacuum.
- Infrared
- Invisible radiation given out by warm objects.
- Insulation
- A material that reduces energy transfer by heating.
- Specific heat capacity
- The energy needed to raise the temperature of 1 kg of a substance by 1 °C.
- Specific latent heat
- The energy needed to change the state of 1 kg of a substance.
- Latent heat of fusion
- The energy needed to melt 1 kg of a substance.
- Latent heat of vaporisation
- The energy needed to boil 1 kg of a substance.
- Heating curve
- A graph of temperature against time as a substance is heated.